Yes it can be used either way. When using the back to face outward you will have a small bevel groove at the joint.
Frame for barn doors can be 1 x 4 or 1 x 6 non pattern material or existing T&G pattern can be ripped and using the square edge as a frame component.
Approx.6.25 #s ea.
Sold by the piece.
Not fire rated
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I would go with a cove moulding, somewhere between 2 and 3 inches?
Certainly,it will self patina nicely or if it's dry,stain or paint it. Use a nailing gun through the tongue. I put 24" 1x3 spacers.
If you seal both sides!
I don't think u would be happy with that